Determine the activation energy from the gradient of an ln k against 1/T plot or from two rate constants at two temperatures, and find the Arrhenius factor A from the intercept, interpreting A as the frequency of correctly oriented collisions.
Tę umiejętność sprawdza 6 zadań wzorowanych na arkuszach IB z lat 2022–2026.
Chemia IBPaper 1A, maj 2026, TZ1wzorowane1 pktzamkniętełatwe (szac.)
What does the pre-exponential (Arrhenius) factor, A, represent in the Arrhenius equation k=Ae−Ea/RT? A. The frequency of collisions with the correct orientation B. The activation energy of the reaction C. The overall rate constant of the reaction D.…
Chemia IBPaper 1A, specimen 2025wzorowane1 pktzamknięteśrednie (szac.)
Which reaction is expected to have the largest Arrhenius factor, A, at a given temperature? A. Cl2(g) + Br2(g) → 2 BrCl(g) B. Cl(g) + CH4(g) → HCl(g) + CH3(g) C. C2H4(g) + HBr(g) → C2H5Br(g) D. Cl(g) + Br(g) → BrCl(g)
Chemia IBPaper 1, maj 2024, TZ1wzorowane1 pktzamknięteśrednie (szac.)
Which statement is correct for the Arrhenius equation? k=Ae−Ea/RT A. As the temperature increases, the value of e−Ea/RT increases. B. At a given temperature, k increases as Ea increases. C. A is the minimum…
Chemia IBPaper 1, maj 2024, TZ2wzorowane1 pktzamkniętetrudne (szac.)
The graph shows plots of ln k against T1 for two reactions, X and Y. Both lines are extended to the vertical axis. Considering the Arrhenius equation lnk=lnA−RTEa, which combination is correct for reactions X and Y?…
Chemia IBPaper 2, maj 2023, TZ2wzorowane2 pktobliczenioweśrednie (szac.)
The rate of a different reaction at 45 °C is four times its rate at 25 °C. Calculate the activation energy, in kJ mol−1, for this reaction, using sections 1 and 2 of the data booklet.
Chemia IBPaper 1, maj 2022, TZ2wzorowane1 pktzamkniętełatwe (szac.)
In the Arrhenius equation, k=Ae−Ea/RT, which statement about the factor A is correct? A. It is the minimum energy needed for a successful collision. B. It is related to the frequency of collisions with the proper orientation. C. It is the…