Zadanie 3b
Wzorowane na: Chemistry HL Paper 2, May 2022, TZ2, pytanie 3(b). Treść, dane i kontekst są zmienione; sprawdzane umiejętności, format i punktacja jak w oryginale.
Darmowe konto pozwoli wrócić do niego później.
Informacja do zadań 3a-3b.
Standard electrode potentials, E⊖, can be used to predict whether a redox reaction is spontaneous. Reactions that are not spontaneous can be driven by electrolysis.
Polecenie
Molten lead(II) bromide undergoes electrolysis in an electrolytic cell at 420 °C, using inert electrodes.
(i) Deduce the half-equation for the reaction at each electrode.
Cathode (negative electrode):
Anode (positive electrode):
(ii) Deduce the overall cell reaction, including state symbols.
Sprawdź rozwiązanieUkryj rozwiązanieKlucz i punktacja
Odpowiedź z klucza
(i) Cathode (negative electrode): Pb2+ + 2 e− → Pb(l) ✔
Anode (positive electrode): 2 Br− → Br2(g) + 2 e−
OR
✔
(ii) PbBr2(l) → Pb(l) + Br2(g)
balanced equation ✔
correct state symbols ✔
Schemat punktowania
(i) [1] for each electrode; a half-equation with electrons on the wrong side scores zero. (ii) M1: balanced equation; M2: correct state symbols (lead is liquid and bromine is a gas at 420 °C). Accept the ionic equation Pb2+ + 2 Br− → Pb + Br2 for M1.