Zadanie 1b

5 pktotwarteśrednie (szac.)Paper 3, listopad 2023, TZ1

Wzorowane na: Chemistry HL Paper 3, November 2023, TZ1, pytanie 1(b). Treść, dane i kontekst są zmienione; sprawdzane umiejętności, format i punktacja jak w oryginale.

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Informacja do zadań 1a-1d.

A food chemistry group investigated how the processing and storage of fruit juice affects its vitamin C (ascorbic acid) content.

Polecenie

Ultraviolet (UV) light is being investigated as a way of killing micro-organisms in juice without heating it, so that less vitamin C is lost. The absorption spectrum of a dilute aqueous solution of sorbic acid, a preservative that is added to some bottled juices, was recorded.

absorption spectrum of a dilute aqueous solution of sorbic acid, absorbance against wavelength from 220 nm to 700 nm

(i) Deduce the region of the electromagnetic spectrum that is absorbed by sorbic acid. Use section 5 of the data booklet.

(ii) Deduce the colour of the dilute solution of sorbic acid and give a reason.

(iii) Suggest why UV treatment is much less effective at killing micro-organisms in a cloudy, pulpy juice than in clear water.

(iv) Identify two ways of slowing down the oxidation of vitamin C in a bottle of juice during storage.

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Odpowiedź z klucza

(i) UV/ultraviolet ✔

(ii) colourless/white «OR no colour» AND no absorption in the visible region/between 400 and 700 nm ✔

(iii) «UV does not reach the micro-organisms because it is» absorbed by other substances in the juice «sugars, vitamins, pigments, aromatic compounds» OR scattered/blocked by suspended particles/pulp ✔

(iv) Any two of:

store at a lower temperature/in a refrigerator ✔

exclude oxygen/air «seal the bottle completely, fill it to the top, pack under nitrogen or vacuum» ✔

add an antioxidant/reducing agent ✔

store in the dark/in an opaque bottle/limit exposure to light ✔

Schemat punktowania

(i) 1 mark: UV. (ii) 1 mark: colourless or white AND a reason that refers to the absence of absorption between 400 and 700 nm; a reason alone or a colour alone earns nothing. (iii) 1 mark: UV is absorbed or scattered before it reaches the micro-organisms; do not accept 'UV waves are too small' or arguments about other wavelengths. (iv) 1 mark each for any two different ways; do not accept 'add additives' alone; accept the correct name of an antioxidant.

Komentarz

The wavelength of a UV photon is irrelevant to the answer to (iii); what matters is that it is removed from the beam before it reaches the cells.

Umiejętności w zadaniu