Zadanie 5a
Wzorowane na: Chemistry HL Paper 2, May 2026, TZ2, pytanie 5(a). Treść, dane i kontekst są zmienione; sprawdzane umiejętności, format i punktacja jak w oryginale.
Darmowe konto pozwoli wrócić do niego później.
Informacja do zadań 5a-5b.
Bromine atoms released from halogenated compounds destroy ozone in the stratosphere in a cycle of two reactions.
Br ∙ (g) + O3(g) → BrO ∙ (g) + O2(g)
BrO ∙ (g) + BrO ∙ (g) → 2 Br ∙ (g) + O2(g)
| Species | ΔHf⊖ / kJ mol−1 |
|---|---|
| Br ∙ (g) | 111.9 |
| BrO ∙ (g) | 125.8 |
| O3(g) | 142.7 |
Polecenie
State the overall reaction of the cycle and determine its enthalpy change, in kJ mol−1.
Sprawdź rozwiązanieUkryj rozwiązanieKlucz CKE i punktacja
Odpowiedź z klucza
Overall reaction: 2 O3 → 3 O2 ✔ «twice the first reaction plus the second reaction»
ΔHreaction: « products reactants = 3(0) − 2(142.7) =» −285.4 «kJ mol−1» ✔
Schemat punktowania
[2] M1 overall equation 2O3 → 3O2; M2 enthalpy change, accept −285 or −285.4; ECF from M1. Accept the halved equation with −142.7 (or −143). The bromine species cancel and their enthalpies of formation are not needed.
Komentarz
The first reaction has to be doubled before the intermediates cancel, so the overall equation is 2O3 → 3O2 and the answer is for two moles of ozone.