Zadanie 18
Which route to chloroethane has an atom economy of 100 %? A. C2H5OH + PCl5 → C2H5Cl + POCl3 + HCl B. C2H6 + Cl2 → C2H5Cl + HCl C. C2H5OH + HCl → C2H5Cl + H2O D. C2H4 + HCl → C2H5Cl
Calculate the atom economy of a reaction as the molar mass of the desired product divided by the total molar mass of all products, explain why it matters in green chemistry, and distinguish it from percentage yield.
Tę umiejętność sprawdza 11 zadań wzorowanych na arkuszach IB z lat 2023–2025.
Which route to chloroethane has an atom economy of 100 %? A. C2H5OH + PCl5 → C2H5Cl + POCl3 + HCl B. C2H6 + Cl2 → C2H5Cl + HCl C. C2H5OH + HCl → C2H5Cl + H2O D. C2H4 + HCl → C2H5Cl
One route to 2-bromopropane is the substitution of propane by bromine in ultraviolet light. C3H8(g) + Br2(g) → C3H7Br(g) + HBr(g) (C3H8 = 44.11 g mol−1, Br2 = 159.80 g mol−1, C3H7Br = 123.00…
For the overall reaction shown above, calculate the atom economy of this route from propane and ethane to propyl ethanoate. Use sections 1 and 7 of the data booklet.
(i) If the reaction has a percentage yield of 80 %, calculate the mass, in g, of benzene that would be produced from 2.0 kg of cyclohexane. (ii) Calculate the atom economy for this reaction, as a percentage.
Propan-2-ol reacts with tetradecanoic acid to produce propan-2-yl tetradecanoate, an ester used in skin creams. C13H27COOH(l) + CH3CH(OH)CH3(l) ⇌ C13H27COOCH(CH3)2(l) + X(l) (i) Identify the by-product X(l). (ii) Calculate the atom economy of this…
(i) The ideal PMI, which corresponds to the greenest possible process, is 1. Estimate the ideal value of each of the other three metrics. (ii) Identify the metric in the table that cannot be affected by the choice of solvent. (iii) Suggest one reason why the…
Two methods of making ethyl ethanoate are compared using the Eco-Scale. The penalty points are given in the table. Method 1: ethanoic acid reacts with ethanol, with concentrated sulfuric acid as the catalyst. The mixture is heated in a microwave reactor for 40…
Ethenyl ethanoate, CH3COOCH=CH2, is the monomer of poly(ethenyl ethanoate). One industrial route makes it from ethene, ethanoic acid and oxygen: Calculate the percent atom economy for…
A simplified overall process produces the ester C5H10O2 as the desired product: 2 C3H5ClO + 2 C2H6O + Ca(OH)2 → 2 C5H10O2 + CaCl2 + 2 H2O The molar masses of C3H5ClO, C2H6O, Ca(OH)2 and C5H10O2 are respectively 92.52,…
Iron is extracted in a blast furnace by reducing iron(III) oxide with carbon monoxide. Fe2O3(s) + 3 CO(g) → 2 Fe(s) + 3 CO2(g) Calculate the percentage atom economy for the production of iron by this reaction. Use section 1 of the data booklet.
Beryllium metal is produced by the electrolysis of beryllium chloride, BeCl2, dissolved in molten sodium chloride. (i) Write the half-equation for the process at the electrode where beryllium metal is produced. (ii) Calculate the atom economy of this…
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