Oxidation of alcohols

Write equations for the oxidation of primary alcohols to aldehydes and then carboxylic acids and of secondary alcohols to ketones with acidified dichromate(VI), explain why tertiary alcohols resist oxidation, and relate distillation versus reflux to the product obtained.

Tę umiejętność sprawdza 19 zadań wzorowanych na arkuszach IB z lat 2022–2026.

Zadania sprawdzające tę umiejętność: 19 Otwórz w wyszukiwarce z filtrami

Chemia IBPaper 2, maj 2026, TZ1wzorowane1 pktotwartełatwe (szac.)

Zadanie 3d

Pentan-2-ol will react with acidified potassium dichromate, K2Cr2O7, which is an oxidizing agent. State the name of the product of this reaction.

Chemia IBPaper 1A, maj 2026, TZ3wzorowane1 pktzamknięteśrednie (szac.)

Zadanie 27

When heated under reflux with excess acidified potassium dichromate(VI), how many of the structural isomers of the alcohol C5H11OH are oxidized to a carboxylic acid? A. 3 B. 7 C. 4 D. 8

Chemia IBPaper 1A, maj 2025, TZ1wzorowane1 pktzamkniętełatwe (szac.)

Zadanie 28

Which alcohol and which conditions would give the highest yield of 3-methylbutanoic acid on oxidation with acidified potassium dichromate(VI)? A. 3-methylbutan-2-ol, reflux B. 3-methylbutan-1-ol, distillation C. 3-methylbutan-1-ol, reflux D.…

Chemia IBPaper 2, listopad 2025, TZ3wzorowane5 pktotwarteśrednie (szac.)

Zadanie 3e

A compound used to make polymers, hexanedioic acid, can be produced by a series of reactions starting from cyclohexane. (i) Deduce how reactant A is related to hex-1-ene. (ii) For the C=O functional group present in intermediate C, state its structural…

  • Tabela do uzupełnienia
  • Materiał graficzny

Chemia IBPaper 1A, listopad 2025, TZ1wzorowane1 pktzamkniętełatwe (szac.)

Zadanie 26

Which compounds are oxidized when heated with acidified potassium dichromate(VI) solution? I. CH3CH2C(CH3)2OH II. (CH3)2CHCH2OH III. CH3CH(OH)CH3 A. I and II only B. I and III only C. II and III only D. I, II and III

Chemia IBPaper 2, maj 2024, TZ2wzorowane1 pktotwarteśrednie (szac.)

Zadanie 1e

When A is refluxed with excess acidified potassium dichromate(VI), K2Cr2O7, the product is compound E, whose molar mass is greater than that of A. From this information alone, identify one functional group in E.

Chemia IBPaper 1, maj 2024, TZ1wzorowane1 pktzamknięteśrednie (szac.)

Zadanie 26

What is the organic product when butan-2-ol, CH3CH(OH)CH2CH3, is heated under reflux with an excess of an acidified oxidizing agent? A. CH3CH2CH2COOH B. CH3COCH2CH3 C. CH3CH2CH2CHO D. CH3CH(OH)CH2CH3

Chemia IBPaper 1, listopad 2024wzorowane1 pktzamknięteśrednie (szac.)

Zadanie 25

Which compound can be oxidized to a carboxylic acid by heating under reflux with an excess of an acidified oxidizing agent? A. CH3CH(OH)CH2CH3 B. (CH3)3COH C. (CH3)2CHCH2OH D. CH3COCH2CH3

Chemia IBPaper 1, maj 2023, TZ2wzorowane1 pktzamknięteśrednie (szac.)

Zadanie 25

Which products could be obtained by heating isomers of C4H10O under reflux with excess acidified potassium dichromate(VI)? I. 2-methylpropanal II. butanone III. butanoic acid A. I only B. II and III only C. I and III only D. I, II and III

Chemia IBPaper 1, listopad 2023, TZ1wzorowane1 pktzamknięteśrednie (szac.)

Zadanie 27

2-Methylpropan-1-ol is heated with an acidified oxidizing agent and the first product is distilled off as it forms. What is this product? A. (CH3)2CHCOOH B. (CH3)2CHCHO C. (CH3)2CHCH2OH D. CH3COCH2CH3

Chemia IBPaper 1, listopad 2023, TZ2wzorowane1 pktzamknięteśrednie (szac.)

Zadanie 27

Butan-1-ol is heated with an acidified oxidizing agent, and the first product formed is distilled off as soon as it forms. Which compound is collected? A. CH3CH2COCH3 B. CH3CH2CH2CH2OH C. CH3CH2CH2CHO D. CH3CH2CH2COOH

Chemia IBPaper 2, maj 2022, TZ1wzorowane1 pktotwartełatwe (szac.)

Zadanie 3e

Compound B is shown below. Deduce what would be observed when each of Compound B and pentan-2-ol is warmed separately with acidified aqueous potassium dichromate(VI).

  • Materiał graficzny

Chemia IBPaper 1, maj 2022, TZ1wzorowane1 pktzamknięteśrednie (szac.)

Zadanie 26

Which procedure is best for converting butan-1-ol into butanoic acid? A. Heat under reflux with an acidified oxidizing agent B. Heat under reflux with a reducing agent C. Heat with an acidified oxidizing agent and distil off the product as it forms D. Heat…

Chemia IBPaper 1, listopad 2022wzorowane1 pktzamknięteśrednie (szac.)

Zadanie 26

Which conditions best favour the oxidation of butan-1-ol to butanal rather than to butanoic acid? A. Excess oxidizing agent, heated under reflux B. Excess oxidizing agent, heated with the product distilled off as it forms C. Limited oxidizing agent, heated…

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