Zadanie 2a
(a) Outline two features of this experiment that ensure that the propanal intermediate is not a major product.
- Materiał graficzny
Write equations for the oxidation of primary alcohols to aldehydes and then carboxylic acids and of secondary alcohols to ketones with acidified dichromate(VI), explain why tertiary alcohols resist oxidation, and relate distillation versus reflux to the product obtained.
Tę umiejętność sprawdza 19 zadań wzorowanych na arkuszach IB z lat 2022–2026.
(a) Outline two features of this experiment that ensure that the propanal intermediate is not a major product.
Pentan-2-ol will react with acidified potassium dichromate, K2Cr2O7, which is an oxidizing agent. State the name of the product of this reaction.
When heated under reflux with excess acidified potassium dichromate(VI), how many of the structural isomers of the alcohol C5H11OH are oxidized to a carboxylic acid? A. 3 B. 7 C. 4 D. 8
The compound X shown below occurs naturally in cocoa and coffee and is used as a flavouring agent. (i) State the name of the functional group found in compound X. (ii) Deduce the IUPAC name of X. (iii) Draw a structural isomer of X taken from a different…
Which alcohol and which conditions would give the highest yield of 3-methylbutanoic acid on oxidation with acidified potassium dichromate(VI)? A. 3-methylbutan-2-ol, reflux B. 3-methylbutan-1-ol, distillation C. 3-methylbutan-1-ol, reflux D.…
Which change represents oxidation of the functional group? A. CH3COCH3 → CH3CH(OH)CH3 B. CH3CH(OH)CH3 → CH3COCH3 C. CH3CH2COOH → CH3CH2CHO D. CH3CH=CH2 → CH3CH2CH3
A compound used to make polymers, hexanedioic acid, can be produced by a series of reactions starting from cyclohexane. (i) Deduce how reactant A is related to hex-1-ene. (ii) For the C=O functional group present in intermediate C, state its structural…
Which compounds are oxidized when heated with acidified potassium dichromate(VI) solution? I. CH3CH2C(CH3)2OH II. (CH3)2CHCH2OH III. CH3CH(OH)CH3 A. I and II only B. I and III only C. II and III only D. I, II and III
When A is refluxed with excess acidified potassium dichromate(VI), K2Cr2O7, the product is compound E, whose molar mass is greater than that of A. From this information alone, identify one functional group in E.
What is the organic product when butan-2-ol, CH3CH(OH)CH2CH3, is heated under reflux with an excess of an acidified oxidizing agent? A. CH3CH2CH2COOH B. CH3COCH2CH3 C. CH3CH2CH2CHO D. CH3CH(OH)CH2CH3
Which compound can be oxidized to a carboxylic acid by heating under reflux with an excess of an acidified oxidizing agent? A. CH3CH(OH)CH2CH3 B. (CH3)3COH C. (CH3)2CHCH2OH D. CH3COCH2CH3
Which products could be obtained by heating isomers of C4H10O under reflux with excess acidified potassium dichromate(VI)? I. 2-methylpropanal II. butanone III. butanoic acid A. I only B. II and III only C. I and III only D. I, II and III
State the name of a compound that forms the carboxylic acid isomer from 3e when it is heated under reflux with an excess of an oxidizing agent.
State the name of a compound that would form the carboxylic acid you drew in part 3e when it is heated under reflux with an excess of an oxidizing agent.
2-Methylpropan-1-ol is heated with an acidified oxidizing agent and the first product is distilled off as it forms. What is this product? A. (CH3)2CHCOOH B. (CH3)2CHCHO C. (CH3)2CHCH2OH D. CH3COCH2CH3
Butan-1-ol is heated with an acidified oxidizing agent, and the first product formed is distilled off as soon as it forms. Which compound is collected? A. CH3CH2COCH3 B. CH3CH2CH2CH2OH C. CH3CH2CH2CHO D. CH3CH2CH2COOH
Compound B is shown below. Deduce what would be observed when each of Compound B and pentan-2-ol is warmed separately with acidified aqueous potassium dichromate(VI).
Which procedure is best for converting butan-1-ol into butanoic acid? A. Heat under reflux with an acidified oxidizing agent B. Heat under reflux with a reducing agent C. Heat with an acidified oxidizing agent and distil off the product as it forms D. Heat…
Which conditions best favour the oxidation of butan-1-ol to butanal rather than to butanoic acid? A. Excess oxidizing agent, heated under reflux B. Excess oxidizing agent, heated with the product distilled off as it forms C. Limited oxidizing agent, heated…
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