Wzorowane na: Chemistry SL Paper 2, November 2025, TZ1, pytanie 1(a). Treść, dane i kontekst są zmienione; sprawdzane umiejętności, format i punktacja jak w oryginale.
Informacja do zadań 1a-1d.
Sulfur is an element present in two of the amino acids from which proteins are built.
(i) The boxes for the 1s and 2s orbitals of a sulfur atom are shown below. Draw the remaining orbitals needed for its ground-state electron configuration, filling and labelling each one. Use section 7 of the data booklet.
(ii) For a sulfur atom, sketch the shapes of the two orbital types found in the third energy level, labelling each one clearly.
(iii) Explain why, on moving down group 16 from oxygen to polonium, the first ionization energy becomes smaller.
(i) boxes added and labelled 2p «three boxes», 3s and 3p «three boxes», with the 3s and 3p boxes drawn above the 2p boxes ✔
1s ↑↓, 2s ↑↓, 2p ↑↓ ↑↓ ↑↓, 3s ↑↓, 3p ↑↓ ↑ ↑ «16 electrons; the two unpaired 3p electrons have parallel spins» ✔
(ii) s orbital drawn as a sphere centred on the origin AND labelled «3s» ✔
p orbital drawn as two lobes along one axis with the node at the origin AND labelled «3p» ✔
(iii) «the outermost electron sits in» a higher energy level, in a shell that lies further out from the nucleus ✔
increased shielding by the inner-shell electrons weakens the pull the nucleus exerts on this outer electron ✔
(i) M1: orbitals labelled 1s, 2s, 2p, 3s, 3p with the third-shell boxes above the second-shell boxes; M2: correct occupancy 2, 2, 6, 2, 4 with Hund's rule obeyed in 3p. (ii) [1] for each correctly shaped and labelled orbital; the p orbital must lie along one axis with its node at the origin (any of the three axes). (iii) M1: outer electron further from the nucleus / higher energy level (an increase in atomic radius alone is not enough); M2: more shielding or weaker attraction.
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ZrobioneOdhaczanie zapisuje się na Twoim koncie, więc wymaga darmowego konta. Zajmuje chwilę i wracasz do tego samego zadania.