Zadanie 2b
(i) Explain why Rb has a lower first ionization energy than strontium, Sr. (ii) Outline why Rb has a lower electronegativity than potassium, K.
Explain trends in atomic radius, ionic radius, first ionization energy, electron affinity and electronegativity across a period and down a group in terms of nuclear charge, shielding and distance from the nucleus, and compare the sizes of isoelectronic ions.
Tę umiejętność sprawdzają 34 zadania wzorowane na arkuszach IB z lat 2022–2026.
(i) Explain why Rb has a lower first ionization energy than strontium, Sr. (ii) Outline why Rb has a lower electronegativity than potassium, K.
(i) Outline why the strength of the metallic bond increases from potassium, K, to calcium, Ca. (ii) Write an equation for the reaction of potassium, K, with water, including state symbols. (iii) Outline why the electronegativity of chlorine is greater than…
Which row correctly describes how the properties of the halogens change down group 17, listed in the order: non-metallic character, boiling point of the element, atomic radius? A. Increases, increases, increases B. Decreases, increases, increases C. Decreases,…
Why is the first ionization energy of potassium lower than that of sodium? A. Potassium has fewer protons in its nucleus than sodium B. The outer electron of potassium is in a higher main energy level, further from the nucleus and more shielded C. Potassium…
Why do halogens form 1− ions? A. Highly exothermic electron affinity, so the atoms gain one electron B. Low ionization energy, so the atoms lose one electron C. High ionization energy, so the atoms gain one electron D. Low electronegativity, so the atoms gain…
Naturally occurring gallium consists of two isotopes: 60 % of the atoms contain 38 neutrons and the remaining 40 % contain 40 neutrons. (i) Use section 7 of the data booklet to deduce the nuclear symbol of the heavier isotope. (ii) Calculate the relative…
Which of these compounds has the weakest ionic bond? A. SrO B. BaO C. SrS D. BaS
Why is the first ionization energy of sulfur greater than that of magnesium? A. The outer electrons of sulfur are further from the nucleus. B. Sulfur atoms have more occupied main energy levels. C. Sulfur atoms have a greater nuclear charge, while the…
Phosphorus occurs as the atom and as several ions. In which row are the species arranged from the smallest radius to the largest? A. P3−, P, P3+, P5+ B. P5+, P3+, P, P3− C. P,…
Which statement explains why the atomic radius decreases across period 3 from magnesium, Mg, to sulfur, S? A. The number of occupied main energy levels increases B. The shielding effect of the inner electrons decreases C. The number of protons in the nucleus…
(i) The boxes for the 1s and 2s orbitals of a sulfur atom are shown below. Draw the remaining orbitals needed for its ground-state electron configuration, filling and labelling each one. Use section 7 of the data booklet. (ii) For a sulfur atom, sketch the…
Titanium is not included in the graph. Use sections 9 and 10 of the data booklet to find its atomic radius and first ionization energy, and annotate the graph with a cross (X) at the position of the data point for titanium.
Suggest what causes the two quantities in the graph to be related in this way.
The data show that the first ionization energy and the atomic radius are related. (i) State what kind of relationship links the two variables. (ii) Compare and contrast the trends observed for the three groups.
The first ionization energies of four elements with consecutive atomic numbers, A, B, C and D, are shown. An element X reacts with oxygen to form an acidic oxide. Which element could be X? A. A B. B C. C D. D
Lithium can be identified in the light emitted by stars and by flames containing lithium compounds. (i) Outline the appearance of the emission spectrum of lithium. The emission spectrum of a one-electron species, such as the Li2+ ion, can be explained…
Outline why the ionic radius of the sulfide ion, S2−, is greater than that of the chloride ion, Cl−.
Which set of ions shows increasing ionic radii? A. Mg2+ < Na+ < O2− < F− B. Mg2+ < Na+ < F− < O2− C. O2− < F− < Na+ < Mg2+ D. Na+ < Mg2+ < F− < O2−
Outline why the first ionization energies of all the elements in the table are positive, whereas the first electron affinities of most of them are negative.
Suggest one reason why the first electron affinity of magnesium is positive.
Suggest reasons why argon has the largest first ionization energy and the largest positive first electron affinity of the elements in period 3. Largest first ionization energy: Largest positive first electron affinity:
Suggest whether the first electron affinity of xenon is greater or smaller than that of argon, and give one reason for your answer.
Explain the steady fall in atomic volume from element 11 to element 13.
Estimate the atomic volume, in cm3 mol−1, of element 20.
Explain why the first ionization energy decreases from beryllium to barium in group 2.
Which properties decrease down group 17, the halogens? I. electronegativity II. first ionization energy III. melting point A. I and II only B. I and III only C. II and III only D. I, II and III
Which property generally decreases as the first ionization energy of elements increases? A. Atomic radius B. Electronegativity C. Non-metallic character D. Acidity of the oxide
On going down group 1 from lithium to caesium, the first ionization energy of the elements decreases. Which property also decreases down the group? A. Electronegativity B. Atomic radius C. Reactivity with water D. Number of occupied energy levels
Which changes are exothermic? I. CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(l) II. Cl(g) + e− → Cl−(g) III. H2O(l) → H2O(g) A. I and II only B. I and III only C. II and III only D. I, II and III
Most oxide ions are . (i) State the number of protons, neutrons and electrons in this ion. (ii) Some oxide ions are . State the term that describes the relationship between and . (iii) The…
Explain why the first ionization energy of magnesium is greater than that of sodium.
Elements X, Y and Z are in the same period of the periodic table. The relative sizes of their atoms are shown below. Which row shows the correct general trends? A. Ionization energy: Z < Y < X; electronegativity: Z < Y < X; acidity of oxide, least to most…
The N–H bonds in compound P and the O–H bonds in water are both polar. State, giving a reason, whether nitrogen or oxygen is the more electronegative element.
Which property of the elements generally increases from left to right across period 3 and decreases down group 17? A. Atomic radius B. Electronegativity C. Metallic character D. Ionic radius
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