Zadanie 15
The diagram shows the energy profile of a reaction. Which expression could give the enthalpy change, ΔH, of this reaction in kJ mol−1? A. +87 − 215 B. −215 + 87 C. +215 − 87 D. −215 − 87
- Materiał graficzny
Classify reactions as exothermic or endothermic from the direction of energy transfer, predict the temperature rise or fall observed in the surroundings during each type, and relate the sign of ΔH to each.
Tę umiejętność sprawdza 26 zadań wzorowanych na arkuszach IB z lat 2022–2026.
The diagram shows the energy profile of a reaction. Which expression could give the enthalpy change, ΔH, of this reaction in kJ mol−1? A. +87 − 215 B. −215 + 87 C. +215 − 87 D. −215 − 87
Which of the following processes are exothermic? I. K(g) → K+(g) + e− II. H2O(g) → H2O(l) III. Ag+(g) + Cl−(g) → AgCl(s) A. I and II only B. I and III only C. II and III only D. I, II and III
The sealed vessel was left for the reaction to proceed. Suggest two properties of the system, other than its colour, that could be measured to follow the progress of the reaction over time, and predict how each would change as the forward reaction proceeds.
Suppose carbonyl dibromide were made by a free-radical chain reaction of carbon monoxide, CO, with bromine vapour, Br2, started by ultraviolet light. The questions below treat this hypothetical route with the bond-enthalpy model. (i) Write an…
The energy profile below was recorded for a reaction. Which pair of statements is consistent with it? In each option the first statement compares the enthalpy of the products with that of the reactants and the second gives the sign of ΔH. A. products…
Which row correctly describes an endothermic reaction? A. The temperature of the surroundings rises and the products are more stable than the reactants. B. The temperature of the surroundings falls and the products are more stable than the reactants. C. The…
A chemical reaction occurs in a mixture that starts at the same temperature as its surroundings. Immediately after the reaction, the mixture is warmer than before. Which row correctly describes the energy changes in the system and in the surroundings as the…
A student stirred 0.030 mol of solid sodium hydrogencarbonate into 40 cm3 of a 1.0 mol dm−3 solution of ethanedioic acid. H2C2O4(aq) + 2 NaHCO3(s) → Na2C2O4(aq) + 2 CO2(g) + 2 H2O(l) The temperature of the solution fell from…
The forward reaction is endothermic, uses platinum as a catalyst, and takes place at 800 K. Sketch the reaction's energy profile both with and without the catalyst present, labelling the activation energies and ΔH.
The potential energy profile of a reaction is shown. Which reaction has this energy profile? A. Cl2(g) → 2 Cl(g) B. CaCO3(s) → CaO(s) + CO2(g) C. N2O4(g) → 2 NO2(g) D. 2 Mg(s) + O2(g) → 2 MgO(s)
The enthalpy change of a reaction is ΔH = +58 kJ mol−1. Which statement about this reaction is correct? A. The reaction is endothermic and the products are less stable than the reactants. B. The reaction is endothermic and the products…
Propenal can be made by the dehydration of propane-1,2,3-triol (glycerol): CH2(OH)CH(OH)CH2OH(l) → CH2=CHCHO(g) + 2 H2O(g) Two related reactions were studied separately. Reaction 1:…
Which statement about the energy changes in a reaction between covalent molecules is correct? A. The enthalpy change of the reaction equals the sum of the bond enthalpies of the bonds broken minus the sum of the bond enthalpies of the bonds formed B. The…
Outline why the first ionization energies of all the elements in the table are positive, whereas the first electron affinities of most of them are negative.
The standard enthalpy change for the following reaction is −92 kJ mol−1. How much energy, in kJ, is released in the reaction below it? H2(g) + Cl2(g) → 2 HCl(g)…
Solid sodium hydroxide, NaOH, is dissolved in water and the temperature of the solution increases. Which diagram shows the enthalpy change for dissolving the solid in water? A. Diagram A B. Diagram B C. Diagram C D. Diagram D
Hydrogen atoms in the gas phase combine to form a covalent bond: H(g) + H(g) → H2(g) Which statement describes the energy change? A. Energy is absorbed and ΔH is positive B. Energy is released and ΔH is positive C. Energy is released…
The conversion of carbon dioxide to methanol is usually carried out over a catalyst containing copper and zinc oxide. (i) Sketch energy profiles for the forward reaction, with and without the catalyst, on the axes shown. Label ΔH and the two activation…
Which changes are exothermic? I. CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(l) II. Cl(g) + e− → Cl−(g) III. H2O(l) → H2O(g) A. I and II only B. I and III only C. II and III only D. I, II and III
Which of these changes are exothermic? I. N2(g) + 3 H2(g) → 2 NH3(g) II. I2(s) → I2(g) III. H2O(g) → H2O(l) A. I and II only B. I and III only C. II and III only D. I, II and III
Which expression gives the enthalpy change, ΔH, of the forward reaction shown in the enthalpy profile? A. II − I B. I − II C. I − III D. III − II
Describe two observations, other than the formation of gas bubbles, that would show that the reaction of sodium with water is exothermic.
Ethane reacts with iodine vapour. C2H6(g) + I2(g) → C2H5I(g) + HI(g) (i) Calculate the enthalpy change of the reaction, ΔH, using section 12 of the data booklet. (ii) Draw and label an enthalpy level diagram for this reaction on the axes below.
Which change is exothermic? A. Cl2(g) → 2 Cl(g) B. H2O(l) → H2O(g) C. CH4(g) → C(g) + 4 H(g) D. H(g) + Br(g) → HBr(g)
The potential energy profile of a reaction is shown. Which statement correctly describes the reaction? A. Endothermic; the products have a lower potential energy than the reactants B. Endothermic; the products are less stable than the reactants C. Exothermic;…
A reaction has an activation energy of 50 kJ mol−1 and an enthalpy change of −70 kJ mol−1. Which potential energy diagram represents this reaction? A. Graph A B. Graph B C. Graph C D. Graph D
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