Zadanie 5f
Wzorowane na: Chemistry HL Paper 2, November 2023, TZ1, pytanie 5(f). Treść, dane i kontekst są zmienione; sprawdzane umiejętności, format i punktacja jak w oryginale.
Darmowe konto pozwoli wrócić do niego później.
Informacja do zadań 5a-5h.
Aluminium has a low density, which is why it is widely used in aircraft and in specialized alloys.
Polecenie
The standard electrode potential, E⊖, of the half-cell
Al3+(aq) + 3 e− ⇌ Al(s)
is −1.66 V.
(i) Calculate the standard cell potential for the reaction
2 Al(s) + 6 H2O(l) → 2 Al3+(aq) + 6 OH−(aq) + 3 H2(g)
Use section 19 of the data booklet.
(ii) Deduce, giving a reason, whether this reaction is thermodynamically spontaneous.
Sprawdź rozwiązanieUkryj rozwiązanieKlucz i punktacja
Odpowiedź z klucza
(i) Ecell⊖ «= −0.83 − (−1.66)» = +0.83 «V» ✔
(ii) spontaneous AND Ecell⊖ is positive / > 0 ✔
Schemat punktowania
(i) [1]; the sign must be given. (ii) [1]. Accept “spontaneous AND ΔG⊖ is negative”.
Komentarz
The reaction is thermodynamically spontaneous, but aluminium does not visibly react with water because its oxide layer makes the reaction very slow.