Reaction mechanisms and the rate-determining step

Evaluate a proposed mechanism by checking that its elementary steps add up to the overall equation and that the slow step matches the rate equation, and distinguish intermediates (formed then consumed) from transition states on energy profiles.

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Zadanie 26Paper 1A, maj 2025, TZ2
wzorowane1 pktzamkniętełatwe (szac.)

Which species is an intermediate in the following reaction mechanism? NOX2(g)+NOX2(g)NOX3(g)+NO(g)\ce{NO2(g) + NO2(g) -> NO3(g) + NO(g)} NOX3(g)+CO(g)NOX2(g)+COX2(g)\ce{NO3(g) + CO(g) -> NO2(g) + CO2(g)} A. NOX2\ce{NO2} B. NOX3\ce{NO3} C. NO\ce{NO} D. COX2\ce{CO2}

Zadanie 26Paper 1A, listopad 2025, TZ3
wzorowane1 pktzamknięteśrednie (szac.)

The following mechanism has been proposed for the reaction between nitrogen(II) oxide and hydrogen. 2NO(g)NX2OX2(g)\ce{2NO(g) <=> N2O2(g)} fast NX2OX2(g)+HX2(g)NX2O(g)+HX2O(g)\ce{N2O2(g) + H2(g) -> N2O(g) + H2O(g)} slow Which rate equation is consistent with this mechanism? A.…

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