Catalysts and alternative reaction pathways

Explain how a catalyst provides an alternative pathway with lower activation energy, sketch energy profiles with and without a catalyst for exothermic and endothermic reactions, and show on a Maxwell-Boltzmann curve why more particles can react; enzymes are biological catalysts.

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Zadanie 6aPaper 2, maj 2025, TZ1
wzorowane12 pktotwartetrudne (szac.)

In the first step, manganese(III) ions formed from the manganate(VII) are complexed by ethanedioate ions. [Mn(HX2O)X6]X3+(aq)+2CX2OX4X2(aq)[Mn(CX2OX4)X2(HX2O)X2]X(aq)+4HX2O(l)\ce{[Mn(H2O)6]^3+(aq) + 2C2O4^2-(aq) -> [Mn(C2O4)2(H2O)2]^-(aq) + 4H2O(l)} (i) Deduce the oxidation state of carbon in [Mn(CX2OX4)X2(HX2O)X2]X\ce{[Mn(C2O4)2(H2O)2]^-}. (ii)…

Zadanie 3cPaper 2, listopad 2025, TZ1
wzorowane11 pktotwartetrudne (szac.)

(i) Concentrated sulfuric acid, HX2SOX4\ce{H2SO4}, is used as the catalyst in the manufacture of propyl ethanoate. Explain how the catalyst affects the reaction. (ii) The conversion of propane into 1-bromopropane, CX3HX8(g)+BrX2(g)CHX3CHX2CHX2Br(g)+HBr(g)\ce{C3H8(g) + Br2(g) -> CH3CH2CH2Br(g) + HBr(g)}

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