Zadanie 1f
Explain how the rate at which the light intensity was falling after 15 minutes in the 44.8 °C run could be determined from the graph.
- Materiał graficzny
Define rate as change in concentration per unit time, calculate average and instantaneous rates from the gradient or tangent of concentration, volume or mass against time graphs, and describe practical ways to follow a reaction (gas volume, mass loss, colour, conductivity).
Tę umiejętność sprawdza 26 zadań wzorowanych na arkuszach IB z lat 2022–2026.
Explain how the rate at which the light intensity was falling after 15 minutes in the 44.8 °C run could be determined from the graph.
(i) Write a balanced equation for the reaction, including state symbols. (ii) Deduce what property of this reaction makes it possible to follow its rate by both methods. (iii) Magnesium carbonate was used in excess so that all of the acid would react.…
In Method 1 the flask containing 25.0 cm3 of the aqueous acid was put on the balance, which was then set to zero; 0.400 g of MgCO3 was added and the reading was noted every 20 seconds until the reaction had stopped. Each point is the mean of…
The student's results are shown below. Each time was measured to ± 0.1 s. Rather than diluting the stock solution, the student prepared every solution separately, weighing the required mass of the solid on a balance reading to ± 0.01 g and making each one up…
The sealed vessel was left for the reaction to proceed. Suggest two properties of the system, other than its colour, that could be measured to follow the progress of the reaction over time, and predict how each would change as the forward reaction proceeds.
Determine, using a suitable construction drawn on the graph, the initial rate at which CO2(g) is released, in g s−1, in the reaction with 1.20 mol dm−3 HNO3(aq).
Which are units for rate of reaction? A. s mol−1 dm3 B. mol dm−3 min C. mol dm−3 min−1 D. mol min−1
Which of the following could be used to follow the progress of the reaction between calcium carbonate and dilute nitric acid? CaCO3(s) + 2 HNO3(aq) → Ca(NO3)2(aq) + H2O(l) + CO2(g) I. A balance recording the mass of the open flask and its contents II. A…
Equal volumes of nitrogen and hydrogen are mixed and react according to the equation below. The volumes of the two reactants are measured at intervals. N2(g) + 3 H2(g) → 2 NH3(g) Which graph shows how the volumes of the two reactants change with time? A.…
The student's results are plotted below. (i) Calculate the average rate at which the hydrogensulfite concentration in the 24 h flask decreased over the 12 days. Include units in your answer. (ii) Before starting, the student wrote this hypothesis: "The longer…
By drawing a suitable line on the graph, determine the rate at which carbon dioxide is released at the start of Experiment 1. Give your answer in cm3 s−1.
The results in Figure 1 were processed to give Figure 2, which shows how the initial rate of reaction varies with the mass of catalyst. (i) Outline how the y-axis values in Figure 2 were obtained from the results in Figure 1. (ii) Suggest, giving a reason,…
State one method that could be used to follow the progress of this reaction and explain how its measurements allow the rate, in mol dm−3 s−1, to be determined.
The concentration of hydrogen peroxide in a reaction mixture was followed for 600 s and the results are plotted in the graph. (i) Determine the instantaneous rate of the reaction, to two significant figures, when [H2O2] = 0.160 mol dm−3.…
The student then followed the reaction with a spectrophotometer, which records the light absorbed by the mixture and so gives the concentration of the dye throughout the reaction. The graph shows [D+] against time for experiment 3. (i) Use the graph to…
Which methods could be used to determine the rate of this reaction? CaCO3(s) + 2 HCl(aq) → CaCl2(aq) + H2O(l) + CO2(g) I. measuring the decrease in mass of the reaction mixture II. measuring the change in absorbance of light by the solution in a…
Nitrogen dioxide, NO2, is one of the brown pollutant gases in photochemical smog. It can react with carbon monoxide, which is also present in polluted air. NO2(g) + CO(g) → NO(g) + CO2(g) (i) Suggest how the rate of this reaction could be…
The oxidation of sulfur dioxide in industry requires a catalyst. (i) State how a catalyst increases the rate of this reaction. (ii) Sketch a Maxwell-Boltzmann distribution curve showing the activation energies with and without a catalyst. (iii) Suggest how the…
Suggest how the rate of this reaction could be determined experimentally.
The graph shows how the concentration of reactant A changes during a reaction. The dashed line is the tangent to the curve at t = 0. Which calculation gives the initial rate of reaction, in mol dm−3 s−1? A. B.…
The graph shows how the concentration of dinitrogen pentaoxide, N2O5, changes with time during its decomposition at constant temperature. What is the average rate of reaction, expressed as the rate of decrease in the concentration of N2O5, over…
Heat treatment at 90 °C is used to destroy spoilage micro-organisms in pineapple juice. The concentration of vitamin C was measured over 56 days in untreated juice and in heat-treated juice from the same batch. (i) Identify the dependent variable in this…
The rate of the reaction 4 PH3(g) → P4(g) + 6 H2(g) can be expressed as the rate of change of the concentration of P4 with respect to time, Δ[P4]/Δt. Which expression is numerically equal to this rate? A.…
Phosphine decomposes according to the equation 4 PH3(g) → P4(g) + 6 H2(g). The rate of the reaction can be expressed as the rate of change of the concentration of P4, Δ[P4]/Δt. Which expression is equal to this rate? A.…
Nitrogen dioxide reacts with fluorine as shown below. 2 NO2(g) + F2(g) → 2 NO2F(g) rate = k[NO2][F2] How does the rate of disappearance of NO2 compare with that of F2? A. NO2 disappears at half the rate of…
The graph shows how the concentration of a reactant changes with time. What initial rate of reaction, in mol dm−3 s−1, can be determined from the graph? A. 0.1 B. 0.2 C. 0.5 D. 2.0
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