Zadanie 1d
Wzorowane na: Chemistry HL Paper 2, May 2026, TZ1, pytanie 1(d). Treść, dane i kontekst są zmienione; sprawdzane umiejętności, format i punktacja jak w oryginale.
Darmowe konto pozwoli wrócić do niego później.
Informacja do zadań 1a-1f.
Nitric acid, HNO3, is manufactured industrially from ammonia in a three-step process known as the Ostwald process.
Polecenie
Nitric acid, HNO3, is strong, while nitrous acid, HNO2, is weak.
(i) Outline the difference between a strong and a weak acid.
(ii) Deduce the Lewis formula and the molecular geometry for the nitrite ion, NO2−.
(iii) State the hybridization of the nitrogen atom in the nitrite ion.
(iv) Explain the stability of the nitrite ion with reference to its Lewis formula.
Sprawdź rozwiązanieUkryj rozwiązanieKlucz CKE i punktacja
Odpowiedź z klucza
(i) a strong acid ionizes/dissociates completely AND a weak acid ionizes/dissociates partially «in aqueous solution» ✔
(ii) M1: Lewis formula of NO2−: N bonded to one O by a double bond and to the other O by a single bond, one lone pair on N, lone pairs completing each O, all in square brackets with a 1− charge «either resonance form; the charge may be shown on the singly bonded O without brackets» ✔
M2: molecular geometry bent/V-shaped «3 electron domains around N, one of them non-bonding» ✔
(iii) sp2 ✔ «three electron domains around N: one N=O, one N–O and one lone pair»
(iv) M1: delocalization of electrons/of the negative charge «over the O–N–O unit» ✔
M2: resonance structures «two equivalent structures differing in which O carries the double bond, so both N–O bonds are identical and of intermediate length and strength» ✔
Schemat punktowania
(i) [1] one marking point: both halves of the contrast are needed. (ii) [2] M1: correct Lewis formula (18 valence electrons); any combination of lines and dots is accepted; penalize missing brackets and/or missing negative charge, but the charge may be placed on the singly bonded O without brackets; either resonance form is accepted. M2: molecular geometry must follow from the Lewis formula drawn (ECF), so a structure with a different number of electron domains is marked for the geometry consistent with it. (iii) [1] sp2; ECF from the Lewis formula drawn in (ii) (three electron domains around N give sp2; a drawing with four domains would give sp3). (iv) [2] M1: delocalization of electrons or of the negative charge; M2: resonance structures (accept resonance hybrid); two equivalent N–O bonds of intermediate length may be offered as the consequence.
Komentarz
Hybridization must follow from the number of electron domains in the drawn Lewis formula, not from memory of the ion.