Equilibrium calculations with ICE tables

Solve equilibrium problems with an initial-change-equilibrium (ICE) table: find K from equilibrium concentrations, or find equilibrium concentrations from K and initial amounts, including cases that need a quadratic or a small-x approximation.

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Zadanie 1cPaper 2, maj 2025, TZ2
wzorowane10 pktobliczeniowetrudne (szac.)

The cyanide ion acts as a ligand in many complex ions, for example hexacyanoferrate(III), [Fe(CN)X6]X3\ce{[Fe(CN)6]^3-}. (i) State the type of bond, as precisely as possible, that joins each cyanide ion to the iron ion. (ii) Deduce the oxidation state of iron in…

Zadanie 1dPaper 1B, maj 2025, TZ3
wzorowane2 pktobliczenioweśrednie (szac.)

A sample of 0.0120 mol of NOX2\ce{NO2} was sealed in a vessel of volume 1.00 dm3\mathrm{dm^3} and kept at 10.0 °C until equilibrium was established. At equilibrium, 0.00860 mol of NOX2\ce{NO2} remained in the vessel. Using the expression below, determine KK for…

Zadanie 31Paper 1A, listopad 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

Nitrogen reacts with hydrogen to form ammonia. NX2(g)+3HX2(g)2NHX3(g)\ce{N2(g) + 3H2(g) <=> 2NH3(g)} A mixture of 1.50 mol of NX2(g)\ce{N2(g)} and 4.20 mol of HX2(g)\ce{H2(g)} was placed in a 1.00 dm3\mathrm{dm^3} container at a certain temperature. At equilibrium the mixture contained…

Zadanie 5gPaper 2, specimen 2025
wzorowane3 pktobliczeniowetrudne (szac.)

The equilibrium constant, KcK_\mathrm{c}, for the reaction in (f) is 6.4×1056.4 \times 10^{-5} at 80 °C. (i) 1.00 dm31.00\ \mathrm{dm^3} of a mixture that is initially 0.20 moldm30.20\ \mathrm{mol\,dm^{-3}} in octadecanoic acid and 0.20 moldm30.20\ \mathrm{mol\,dm^{-3}} in butan-2-ol is…

Zadanie 30Paper 1A, specimen 2025
wzorowane1 pktzamknięteśrednie (szac.)

The equation for a reaction between gases X and Y is: 2X(g)+Y(g)2Z(g)\ce{2X(g) + Y(g) <=> 2Z(g)} At equilibrium at 700 K the concentrations of X, Y and Z are 0.50 moldm30.50\ \mathrm{mol\,dm^{-3}}, 0.40 moldm30.40\ \mathrm{mol\,dm^{-3}} and 1.0 moldm31.0\ \mathrm{mol\,dm^{-3}} respectively.…

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