Chemistry HL Paper 1A, May 2025, TZ1

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IB, sylabus 2023 (egzaminy od 2025) | 40 zad. w bazie

Zadanie 2Paper 1A, maj 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

The letters below stand for four species, not for element symbols. Which pair of species has an identical number of outer-shell electrons? X1531X215231JX2\ce{^{31}_{15}J^{2-}}, X1840X218240LX+\ce{^{40}_{18}L^{+}}, X1939X219239MX+\ce{^{39}_{19}M^{+}}, X1632X216232QX2+\ce{^{32}_{16}Q^{2+}} A. J and M B. L and Q C.…

Zadanie 11Paper 1A, maj 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

Which row lists these molecules in order of increasing bond angle? A. NFX3\ce{NF3}, SiHX4\ce{SiH4}, HCHO\ce{HCHO}, CX2HX2\ce{C2H2} B. SiHX4\ce{SiH4}, NFX3\ce{NF3}, HCHO\ce{HCHO}, CX2HX2\ce{C2H2} C. NFX3\ce{NF3}, HCHO\ce{HCHO}, SiHX4\ce{SiH4}, CX2HX2\ce{C2H2} D. CX2HX2\ce{C2H2}, HCHO\ce{HCHO},…

Zadanie 12Paper 1A, maj 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

A mixture of biphenyl, CX12HX10\ce{C12H10}, and 4-phenylphenol, CX12HX10O\ce{C12H10O}, was separated by thin-layer chromatography on a polar silica plate, using the non-polar solvent cyclohexane as the mobile phase. What are the position and the retardation factor…

Zadanie 13Paper 1A, maj 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

In the 19th century benzene was proposed to be cyclohexa-1,3,5-triene, a ring with three localized carbon-carbon double bonds. Which observation contradicts this model? A. Benzene is a planar molecule with bond angles of 120° B. The enthalpy of hydrogenation…

Zadanie 14Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

Phosphorus occurs as the atom and as several ions. In which row are the species arranged from the smallest radius to the largest? A. PX3\ce{P^{3-}}, P\ce{P}, PX3+\ce{P^{3+}}, PX5+\ce{P^{5+}} B. PX5+\ce{P^{5+}}, PX3+\ce{P^{3+}}, P\ce{P}, PX3\ce{P^{3-}} C. P\ce{P},…

Zadanie 16Paper 1A, maj 2025, TZ1
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Which pair of elements would react together most vigorously? A. Na(s)\ce{Na(s)} and IX2(s)\ce{I2(s)} B. Cs(s)\ce{Cs(s)} and IX2(s)\ce{I2(s)} C. Na(s)\ce{Na(s)} and FX2(g)\ce{F2(g)} D. Cs(s)\ce{Cs(s)} and FX2(g)\ce{F2(g)}

Zadanie 22Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

Which equation represents both the standard enthalpy of formation, ΔHf\Delta H_\mathrm{f}^\ominus, of a compound and the standard enthalpy of combustion, ΔHc\Delta H_\mathrm{c}^\ominus, of an element? A. C(s)+12OX2(g)CO(g)\ce{C(s) + 1/2 O2(g) -> CO(g)} B.…

Zadanie 23Paper 1A, maj 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

A student stirred 0.030 mol of solid sodium hydrogencarbonate into 40 cm3\mathrm{cm^3} of a 1.0 moldm3\mathrm{mol\,dm^{-3}} solution of ethanedioic acid. HX2CX2OX4(aq)+2NaHCOX3(s)NaX2CX2OX4(aq)+2COX2(g)+2HX2O(l)\ce{H2C2O4(aq) + 2NaHCO3(s) -> Na2C2O4(aq) + 2CO2(g) + 2H2O(l)} The temperature of the solution fell from…

Zadanie 24Paper 1A, maj 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

The table shows standard enthalpies of combustion. Substance ΔHc\Delta H_\mathrm{c}^\ominus / kJmol1\mathrm{kJ\,mol^{-1}} CX4HX10(g)\ce{C4H10(g)} −2878 CX3HX6(g)\ce{C3H6(g)} −2058 CHX4(g)\ce{CH4(g)} −891 Which expression gives the enthalpy change, in kJmol1\mathrm{kJ\,mol^{-1}}, of the…

Zadanie 25Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

Which reaction has the largest positive entropy change? A. 2SOX2(g)+OX2(g)2SOX3(g)\ce{2SO2(g) + O2(g) -> 2SO3(g)} B. NHX4Cl(s)NHX3(g)+HCl(g)\ce{NH4Cl(s) -> NH3(g) + HCl(g)} C. HX2(g)+ClX2(g)2HCl(g)\ce{H2(g) + Cl2(g) -> 2HCl(g)} D. NaOH(aq)+HCl(aq)NaCl(aq)+HX2O(l)\ce{NaOH(aq) + HCl(aq) -> NaCl(aq) + H2O(l)}

Zadanie 26Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

One route to 2-bromopropane is the substitution of propane by bromine in ultraviolet light. CX3HX8(g)+BrX2(g)CX3HX7Br(g)+HBr(g)\ce{C3H8(g) + Br2(g) -> C3H7Br(g) + HBr(g)} (CX3HX8\ce{C3H8} = 44.11 gmol1\mathrm{g\,mol^{-1}}, BrX2\ce{Br2} = 159.80 gmol1\mathrm{g\,mol^{-1}}, CX3HX7Br\ce{C3H7Br} = 123.00…

Zadanie 27Paper 1A, maj 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

30 cm3\mathrm{cm^3} of butane was completely burned in 250 cm3\mathrm{cm^3} of oxygen according to the following equation. 2CX4HX10(g)+13OX2(g)8COX2(g)+10HX2O(l)\ce{2C4H10(g) + 13O2(g) -> 8CO2(g) + 10H2O(l)} What volume of oxygen remains unreacted, measured at the original conditions? A. 55…

Zadanie 29Paper 1A, maj 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

The gas-phase decomposition below has reached equilibrium in a sealed vessel: PClX5(g)PClX3(g)+ClX2(g)\ce{PCl5(g) <=> PCl3(g) + Cl2(g)} ΔH=+88 kJmol1\Delta H^\ominus = +88\ \mathrm{kJ\,mol^{-1}} The pressure is then changed. Which row pairs the change correctly with the direction in which the…

Zadanie 30Paper 1A, maj 2025, TZ1
wzorowane1 pktzamknięteśrednie (szac.)

The following results were obtained for the reaction between bromate(V) ions, bromide ions and hydrogen ions in aqueous solution. BrOX3X(aq)+5BrX(aq)+6HX+(aq)3BrX2(aq)+3HX2O(l)\ce{BrO3^-(aq) + 5Br^-(aq) + 6H+(aq) -> 3Br2(aq) + 3H2O(l)} Experiment Initial [BrOX3X\ce{BrO3^-}] / moldm3\mathrm{mol\,dm^{-3}} Initial…

Zadanie 32Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

Which two species can act both as Brønsted–Lowry acids and as Brønsted–Lowry bases? A. HX2COX3\ce{H2CO3} and COX3X2\ce{CO3^{2-}} B. HCOX3X\ce{HCO3-} and SOX3X2\ce{SO3^{2-}} C. HCOX3X\ce{HCO3-} and HSOX3X\ce{HSO3-} D. HX2SOX3\ce{H2SO3} and HSOX3X\ce{HSO3-}

Zadanie 34Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

Sulfur has different oxidation states in hydrogen sulfide, HX2S\ce{H2S}, and in sulfurous acid, HX2SOX3\ce{H2SO3}. Which pair of values is correct? A. HX2S\ce{H2S}: +2; HX2SOX3\ce{H2SO3}: +4 B. HX2S\ce{H2S}: −2; HX2SOX3\ce{H2SO3}: +6 C. HX2S\ce{H2S}: −2; HX2SOX3\ce{H2SO3}: +4 D.…

Zadanie 35Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

Part of the reactivity series of metals is shown, from the most reactive to the least reactive. Mg, Al, Mn, Zn, Fe, Ni, Sn, Pb, Cu, Ag Which reaction is spontaneous? A. FeX2+(aq)+Ni(s)NiX2+(aq)+Fe(s)\ce{Fe^{2+}(aq) + Ni(s) -> Ni^{2+}(aq) + Fe(s)} B.…

Zadanie 36Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

Which alcohol and which conditions would give the highest yield of 3-methylbutanoic acid on oxidation with acidified potassium dichromate(VI)? A. 3-methylbutan-2-ol, reflux B. 3-methylbutan-1-ol, distillation C. 3-methylbutan-1-ol, reflux D.…

Zadanie 38Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

What is the role of the hydroxide ion in the reaction of 2-bromopropane with warm aqueous sodium hydroxide? CHX3CHBrCHX3+OHXCHX3CH(OH)CHX3+BrX\ce{CH3CHBrCH3 + OH- -> CH3CH(OH)CH3 + Br-} A. Nucleophile and Lewis acid B. Electrophile and Lewis acid C. Nucleophile and Lewis base D. Electrophile…

Zadanie 40Paper 1A, maj 2025, TZ1
wzorowane1 pktzamkniętełatwe (szac.)

Benzene undergoes nitration when it is warmed with a mixture of concentrated nitric and sulfuric acids. Which species attacks the benzene ring in this substitution reaction? A. HNOX3\ce{HNO3} B. NOX2\ce{NO2}• C. NOX2X\ce{NO2-} D. NOX2X+\ce{NO2+}